Chiral catalyst immobilization and recycling
WebDec 15, 2007 · The recycling tests showed a loss of activity that was attributed to the surface modification of the catalyst.Graphical abstractView high quality image (135K)Highlights SiO2 supports were ... WebA simple method for the synthesis of a MeO-PEG-supported chiral ferrocenyl oxazoline carbinol ligand has been developed. The chiral ligand was successfully applied to the catalytic asymmetric addition of diethylzinc to aryl aldehydes, affording secondary alcohols in high yields and with excellent enantioselectivities (up to 94% ee). The chiral ligand …
Chiral catalyst immobilization and recycling
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WebChiral Catalyst Immobilization and Recycling book. Read reviews from world’s largest community for readers. Homogeneous asymmetric catalysis offers relia... WebThe catalytic properties of olefin metathesis ruthenium complexes bearing N-heterocyclic carbene ligands with stereogenic centers on the backbone are described. Differences in catalytic behavior depending on the backbone configurations of symmetrical and unsymmetrical NHCs are discussed. In addition, an overview on asymmetric olefin …
WebJan 17, 2011 · Inherently chiral calixarenes, whose chirality is based on the absence of a planar symmetry or an inversion center in the molecules as a whole through the asymmetric array of several achiral groups upon the three-dimensional calix-skeletons, are challenging and attractive chiral molecules, because of their potential in supramolecular chemistry. …
WebChiral Catalyst Immobilization and Recycling Edited by D. E. De Vos, I. F. J. Vankelecom, P. A. Jacobs Other Titles of Interest B. Cornils / W. A. Herrmann Applied … WebWe present the use of Pd-complex-containing supported ionic liquid phases (SILPs) as a novel approach for continuous-flow allylic alkylation of N-nucleophiles. This immobilization strategy gave simple access to air-tolerating catalyst frameworks, providing rapid and convenient access to various achiral and chiral N-allylation products.
WebDec 4, 2006 · Immobilization of highly functionalized (bio)molecules onto the surfaces of solid supports is a frequent requirement in the development of reusable catalysts, 1 chromatographic materials, 2 sensors, 3 chip-type analytical devices, 4 and solid-phase synthesis strategies. 5 Most importantly, dedicated linking procedures must preserve the …
WebHomogeneous asymmetric catalysis offers reliable results and the possibility to 'tune' the catalysis on a rational basis. A pitfall, however, is that the separation of the catalyst from the starting material and products is difficult and often results in the loss of the catalytic material. Immobilization offers a potential solution for the user ... how many school shootings in 1950WebOct 15, 2000 · Immobilization offers a potential solution for the user of enantioselective catalysts in industrial processes and laboratories. Heterogeneous catalysis allows … how did beowulf\u0027s warriors break comitatusWebMar 2, 2004 · Alkaloids such as cinchonidine, quinine and N-methylephedrine have been N-alkylated using polymeric benzyl halides or co-polymerized and then N-alkylated, thus affording a series of polymer-supported chiral ammonium salts which have been employed as phase-transfer catalysts in the asymmetric benzylation of an N … how did beowulf\\u0027s warriors break comitatusWebJun 11, 2024 · A novel, efficient approach for the functionalization of microcrystalline cellulose (MCC) is presented. The as-obtained material allows the immobilization of chiral dirhodium catalysts preserving their enantioselectivity in asymmetric cyclopropanation reactions. As model, microcrystalline cellulose is modified with a polyethylene glycol … how many school shootings have there beenWebApr 26, 2013 · The main strategy used to prepare chiral heterogeneous catalysts is the immobilization of homogeneous catalysts over insoluble supports (De Vos et al. 2000; Heitbaum et al. 2006), and any interaction (covalent, ionic, coordinative, H-bond, van der Waals, etc.) between catalyst and support can be used to immobilize a catalyst (Fig. 2). … how many school shootings in 2000WebChiral Catalyst Immobilization and Recycling Dirk De Vos (Editor), Ivo F. J. Vankelecom (Editor), Pierre A. Jacobs (Editor) E-Book 978-3-527-61315-1 July 2008 $165.00 O-Book … how many school shootings in 2016WebDec 15, 2007 · The immobilization of chiral homogeneous catalysts on solid insoluble supports is the most common method to prepare chiral heterogeneous catalysts, and … how many school shootings in 1990